Decent shot. Lighting on the face is good. Something bugs me about it and I can't seem to put my finger on it. Not sure if it's the backdrop, that its too bright or that more of his shoulders aren't showing.
I think it is the pupils are dialated and the white is not white on the background. I am on my iPad not my calibrated monitor so I will say that is a maybe but it does not look like it would register 255 and his teeth are brighter white then the background. I might have shot this on grey instead.
The shot was taken in a darkened room, thus the dilated pupils. As to the white teeth and eyes, his really are that bright. This was an impromptu shot. I was set up in a new working area I've created in my apartment. I've made accommodation for a background but haven't purchased or set one up as of yet.
The white bkg you have is ok. To get the pupils smaller just turn on a light and bounce it off a wall just watch it so it doesn't create too much fill. Whatever your using for a main you can add a light bulb to that to help the eyes.
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